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Syntheses, Structures, and Luminescent Properties of [Bis(iminoalkyl)pyridine]cadmium(II) Complexes

✍ Scribed by Rui-Qing Fan; Dong-Sheng Zhu; Ying Mu; Guang-Hua Li; Yu-Lin Yang; Qing Su; Shou-Hua Feng

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 169 KB
Volume: 2004
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200400443

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~