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Syntheses, structures and characterizations of Rb3Na(MO4)2 (M = Mo, W) crystals

โœ Scribed by Bai, Chunyan; Lei, Chen; Pan, Shilie; Wang, Ying; Yang, Zhihua; Han, Shujuan; Yu, Hongwei; Yang, Yun; Zhang, Fangyuan

Book ID
122218791
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
1013 KB
Volume
33
Category
Article
ISSN
1293-2558

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Syntheses, Crystal Structures, and Prope
Syntheses, Crystal Structures, and Properties of Novel Heterooctametallic Clusters Na2M'2[M3O4(O2CEt)8]2 (M' = Fe, Cr, Mo; M3 = Mo3, MoW2, W3)
โœ Li Xu; Zhaohui Li; Huang Liu; Jinshun Huang; Qianer Zhang ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 628 KB

A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120ยฐC to afford