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Syntheses and characterization of two oxoborates, (Pb3O)2(BO3)2MO4 (M=Cr, Mo)

โœ Scribed by Xuean Chen; Fangping Song; Xinan Chang; Hegui Zang; Weiqiang Xiao


Book ID
104030462
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
455 KB
Volume
182
Category
Article
ISSN
0022-4596

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A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120ยฐC to afford