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Syntheses, Structures, and Characterization of New Lead(II)—Tellurium(IV)—Oxide Halides: Pb3Te2O6X2 and Pb3TeO4X2 (X: Cl or Br).

✍ Scribed by Yetta Porter; P. Shiv Halasyamani


Publisher
John Wiley and Sons
Year
2003
Weight
67 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Red crystals of [H 3 O ´(dibenzo-18-crown-6)][Te 2 Br 9 ] (1) were isolated from a solution of TeBr 4 and dibenzo-18crown-6 in CH 3 CN containing a small amount of hydrobromic acid. The compound crystallizes in the triclinic space group P 1 with the cell dimensions a = 9.010(2), b = 13.403(3), c = 1