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Syntheses of urethano-, amido- and sulfonamido-[60]fullerenes by nucleophilic substitutions with 1,2-(2,3-dihydro-1H-azirino)-[60]fullerene

โœ Scribed by Johannes Averdung; Christian Wolff; Jochen Mattay


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
133 KB
Volume
37
Category
Article
ISSN
0040-4039

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Functionalization of [60]fullerene by ph
โœ Christina Siedschlag; Heinrich Luftmann; Christian Wolff; Jochen Mattay ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 348 KB

Fullerene is irradiated in the presence of the electron transfer sensitizer 9,10dicyanoanthracene (DCA) under cosensitization with biphenyl. The generated radical cation C6o ยฐ+ reacts with H-donors such as tert-butylmethyl ether, propionaldehyde and alcohols to give 1:1-edduets, the 1-substituted 1,