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Functionalization of [60]fullerene by photoinduced electron transfer (PET): Syntheses of 1-substituted 1,2-dihydro[60]fullerenes

✍ Scribed by Christina Siedschlag; Heinrich Luftmann; Christian Wolff; Jochen Mattay

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 348 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00078-1

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✦ Synopsis

Fullerene is irradiated in the presence of the electron transfer sensitizer 9,10dicyanoanthracene (DCA) under cosensitization with biphenyl. The generated radical cation C6o °+ reacts with H-donors such as tert-butylmethyl ether, propionaldehyde and alcohols to give 1:1-edduets, the 1-substituted 1,2-dihydro[60]fullerenes.

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