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Syntheses of gold-manganese and gold-rhenium clusters, [(Ph3PAu)3M(CO)4] and [(Ph3PAu)4M(CO)4]+ (M  Mn, Re), and the crystal structure of [(Ph3PAu)4Mn(CO)4]BF4

✍ Scribed by Brian K. Nicholson; Michael I Bruce; Omar bin Shawkataly; Edward R.T. Tiekink


Book ID
107812164
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
547 KB
Volume
440
Category
Article
ISSN
0022-328X

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Eight-Coordinate Metal Carbonyls Contain
✍ Prof. John E. Ellis; Kai-Ming Chi; Dr. Anthony-J. DiMaio; Scott R. Frerichs; Jas 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 394 KB

four coordinate 4, and five coordinate 5 have identical g, and g,l to 2. UV-vis spectra show that 5 does not dispropor-[Ni(C6H,CH=N-NHCSNH2),1C1Z 4 [Ni(C,H,OHCH=N-NHCSNH,)(C,H,CH="HCSNHCSNHz)]Clz 5 tionate to 1 and 4. The Nil complexes are therefore fourcoordinate with an N,S, environment. We looke