Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides
✍ Scribed by Grossman, Robert B.; Doyle, Ruth Ann.; Buchwald, Stephen L.
- Book ID
- 121875827
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 683 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0276-7333
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Stereospecific polymerization andasymmetric oligomerization of allylsilanes were investigated by using C2-and C,-symmetric zirconocene catalysts. Isotactic and syndiotactic poly(allylsi1ane)s were produced with rac-ethylenebis(4,5,6,7-tetrahydro-1 -indenyl)zirconium dichloride (1) and diphenylmethyl
## Abstract Optical resolution of ethylenebis(4,5,6,7‐tetrahydro‐1‐indenyl) complexes of zirconium and hafnium was performed by using cellulose tris(3,5‐dimethylphenylcarbamate) coated on silica‐gel (Chiralcel OD) as a chiral stationary phase for HPLC. The biphenyl‐2,2′‐diolate complexes were compl