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Syntheses of di-heterocyclic compounds; pyrazolylimidazoles and isoxazolylimidazoles
✍ Scribed by Zhengming Li; Jimin Li; Guofeng Jia
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 154 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7163
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✦ Synopsis
Fifteen substituted di-heterocyclic imidazoles were prepared. Ten substituted pyrazolylimidazoles were obtained by cyclocondensation of ␣-oxo-␣-imidazolylketene dithioacetal or N,S-acetals with hydrazine and by ring-chain transformation of cyclic ␣-oxo-␣-imidazolylketene N,O-acetals. Five isoxazolylimidazoles were obtained by reaction of ␣-oxo-␣-imidazolylketene dithioacetal with hydroxylamine.
📜 SIMILAR VOLUMES
The new compound C 10 H 6 P(S)[NSi(CH 3 ) 3 ] 2 P(S) (3) which contains a P 2 N 2 heterocycle has been prepared in low yield by partial thermal decomposition of 1 3 )SP(S) 2 ] ± (2). Reaction of 2 with potassium hydroxide in acetonitrile gives the completely desilylated product 4). The structures o