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Syntheses of benzomorphan and related compounds. Part III. An alternate synthesis of 3-substituted-1,2,3,4,5,6-hexahydro-8-hydroxy-2,6-methano-6,11-dimethyl-3-benzazocine

✍ Scribed by T. Kametani; K. Kigasawa; M. Hayasaka; K. Wakisaka; F. Satoh; T. Aoyama; H. Ishimaru


Book ID
112122500
Publisher
Journal of Heterocyclic Chemistry
Year
1971
Tongue
English
Weight
229 KB
Volume
8
Category
Article
ISSN
0022-152X

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Beckman cleavage of 1,2,3,4,5,6-hexahydr
✍ Brian Iddon; Donald Price; Hans Suschitzky; David I.C. Scopes πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 236 KB

The title reaction gave 1,2,3,4-tetrahydro-3,6-dimethyl-3benzazocine-2-carbonitrile 18) which showed some expected and some unexpected properties.