𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Syntheses of 3H- and 2H-labeled (16S)-15-deoxy-16-hydroxy-16-methyl-5-thiaprostaglandin E1 methyl esters

✍ Scribed by Satoshi Sugiura; Toshio Tanaka; Kiyoshi Bannai; Seizi Kurozumi

Publisher
John Wiley and Sons
Year
1991
Tongue
French
Weight
498 KB
Volume
29
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The syntheses of [7‐^2^H]‐, [7‐^3^H]‐, and [2,2,3,3,4,4‐^2^H~6~]‐(16__S__)‐15‐deoxy‐16‐ hydroxy‐16‐methyl‐5‐thiaprostaglandin E~1~ methyl ester (2, 3, and 4) are described. Both 7‐labeled compounds, 2 and 3, were prepared from the Δ^7^‐precursor (11) by treatment with in‐situ generated tributyltin deuteride and [^3^H]hydride, respectively. The hexa‐deuterated compound 4 was prepared starting from tetrahydrofuran‐d~8~

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis and Prope
ChemInform Abstract: Synthesis and Properties of 4N,13N-Bis(3′-hydroxy-6′-methyl-4′- oxo-4H- pyranyl-2′-methylene)-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane.
✍ F. BADEA; A. STOICA; M. T. CAPROIU; T. CONSTANTINESCU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Syntheses and Structures of C-Monoamino-
Syntheses and Structures of C-Monoamino-P-ferriophosphaalkenes[(η5-C5Me5)(CO)2FeP=CR1(NR3.0.CO;2-6/asset/equation/tex2gif-stack-1.gif?v=1&t=h5lehpiu&s=ab1cef7d5696b315a822f8407071feb16d2c4cb5" class="inlineGraphic">)] (R1 = Ph, tBu, 3,4,5-(MeO)3C6H2;NR3.0.CO;2-6/asset/equation/tex2gif-stack-2.gif?v=1&t=h5lehpiu&s=2f12a99bda7953d0b3084c39432c3f70455d15f1" class="inlineGraphic"> = NMe2, Piperidino)
✍ Lothar Weber; Stefan Kleinebekel; Annette Rühlicke; Hans-Georg Stammler; Beate N 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB 👁 2 views
Structural Characterization and Intramol
Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands Tp3.0.CO;2-C/asset/equation/tex2gif-sup-3.gif?v=1&t=h5lp536o&s=a03c9eb1fe277a993afb16d61a4b5e5e1fd6ae14" class="inlineGraphic"> (X=Me, H, Br) and Tp3.0.CO;2-C/asset/equation/tex2gif-sup-4.gif?v=1&t=h5lp536o&s=f62756419e66415fd41eb92c51dc480468265b22" class="inlineGraphic">
✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.

A (surface-enhanced) Raman spectroscopic
A (surface-enhanced) Raman spectroscopic study of the adsorption of S2O3.0.CO;2-4/asset/equation/tex2gif-stack-1.gif?v=1&t=h5kawjw4&s=16a98db97a533d73da733e50af96b898e4b6fb9a" class="inlineGraphic">− and SCN− on a silver deposit
✍ D. Gonnissen; W. Langenaeker; A. Hubin; P. Geerlings 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB 👁 1 views

The study of the adsorption behaviour of SCN-and at a silver substrate contributes substantially to an S 2 O 3 2improved insight into the electrochemical formation of a silver image in photographic development processes. (Surface-enhanced) Raman (SER) spectroscopy and quantum chemical calculations r