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SYNTHESES INVOLVING UTILIZATION OF ALLYLMAGNESIUM BROMIDE IN THE GRIGNARD REACTION

โœ Scribed by HENZE, HENRY R.; ALLEN, BRUCE B.; LESLIE, WILLIAM B.


Book ID
120274302
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
602 KB
Volume
07
Category
Article
ISSN
0022-3263

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The role of impurities in the reactions
โœ Richard B. Allen; Ronald G. Lawler; Harold R. Ward ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel