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Syntheses de l'Acide (2R, 3S); (2S, 3R) Agarique (14C-4) et de l'Acide (2R, 3R); (2S, 3S) Agarique (3H-4,4,5,5)

✍ Scribed by J. P. Lellouche; J. P. Beaucourt; L. Pichat

Publisher
John Wiley and Sons
Year
1984
Tongue
French
Weight
286 KB
Volume
21
Category
Article
ISSN
0022-2135

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✦ Synopsis

Epoxy ring opening of 2 and 2 with [ l -1 4 C ] hexadecyl copper lo gave respectivezy t h e analog 4 of agaric acid trimethyl e s t e r and methy2 b -1 4 ~J a g a r i c a t e 5, which-was hydrolysed t o -& by Zithium hy-&oxide i n I, 2-dimethoxyethane (DME).

Epoxy ring trans opening of -2 with d i e t h y l I-hexadecynyZatane 9 qave the aZcynyZ derivative which was saturated with t r i t i u m i n presence of Pd/C t o lead t o 5. A f t e r hydroZysis (LioH + DMEI, & was obtained.

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