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Syntheses, Crystal Structures, and Properties of the Novel Thioborates KBa4(BS3)3 and K4Ba11(BS3)8S.

✍ Scribed by A. Hammerschmidt; C. Jansen; J. Kueper; C. Koester; B. Krebs


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Novel Alkaline Earth Metal Chalcogenobor
✍ A. Hammerschmidt; C. KΓΆster; J. KΓΌper; A. Lindemann; B. Krebs πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 German βš– 143 KB πŸ‘ 2 views

Systematic studies on quaternary thio-and selenoborates containing heavier alkaline earth metal cations led to the two new isotypic crystalline phases Sr 4.2 Ba 2.8 (BS 3 ) 4 S and Ba 7 (BSe 3 ) 4 Se. Both compounds consist of trigonal-planar BQ 3 (Q = S, Se) units, isolated Q 2Β± anions and the corr