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Syntheses and structures of two novel Ag(I) complexes: [μ3-2-(4-pyridyl)ethanesulfonato-N,O,O′]-aqua-silver(I) and melamine-[2-(4-pyridyl)ethanesulfonato-N]-silver(I)

✍ Scribed by Jian Zhang; Zhao-Ji Li; Yi-Hang Wen; Yao Kang; Jian-Kai Cheng; Yuan-Gen Yao


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
230 KB
Volume
697
Category
Article
ISSN
0022-2860

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## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi