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Syntheses and Structures of the New Quaternary Compounds Ba4Nd2Cd3Se10 and Ba4Ln2Cd3S10 (Ln=Sm, Gd, Tb)

✍ Scribed by Yuting Yang; James A. Ibers

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
188 KB
Volume
149
Category
Article
ISSN
0022-4596

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✦ Synopsis

The compounds Ba4Nd2Cd3Se10 and Ba4Ln2Cd3S10 (Ln ‫؍‬ Sm, Gd, Tb) have been synthesized at 1173 K with the use of a BaBr2/ KBr eutectic 6ux. These isostructural compounds crystallize as racemic twins in space group Cmc21 of the orthorhombic system in cells of (Ln, Q, a, b, c (A s ), T (K)

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