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Syntheses and Structures of Alkylaluminum Complexes with a Tridentate Amido Ligand, Al(CH3)2(Et2NCH2CH2NCH2CH2NEt2) and Al3(CH3)8(Et2NCH2CH2NCH2CH2NEt2)

✍ Scribed by Trepanier, Steven J.; Wang, Suning


Book ID
126258648
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
535 KB
Volume
13
Category
Article
ISSN
0276-7333

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The thermal decomposition of [Me 2 GaΒ±N( i Bu)SnMe 3 ] 2 (prepared by the reaction of [Me 2 SnN i Bu] 3 with GaMe 3 in a 1 : 3 molar ratio) in an evacuated, sealed tube at 160 Β°C forms [MeGaN i Bu] 6 in high yield and SnMe 4 . Mass, 1 H and 13 C NMR as well as some IR and Raman spectroscopic data ar