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Syntheses and structures of AgLnS2 (LnSmYb) compounds

✍ Scribed by van der Lee, A.; van de Belt, R.; Wiegers, G.A.

Book ID
122914921
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
748 KB
Volume
178
Category
Article
ISSN
0925-8388

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The compounds Ba4Nd2Cd3Se10 and Ba4Ln2Cd3S10 (Ln ‫؍‬ Sm, Gd, Tb) have been synthesized at 1173 K with the use of a BaBr2/ KBr eutectic 6ux. These isostructural compounds crystallize as racemic twins in space group Cmc21 of the orthorhombic system in cells of (Ln, Q, a, b, c (A s ), T (K)