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Syntheses and Structural Characterization of a One-Dimensional Chain, Two-Dimensional Noninterpenetrated Grid, and Three-Dimensional Polycatenane Coordination Polymers Assembled from Flexible Bidentate Imidazolyl Ligands

โœ Scribed by Jin, Shouwen; Chen, Wanzhi; Qiu, Huayu


Book ID
126447368
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
641 KB
Volume
7
Category
Article
ISSN
1528-7483

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Two novel complexes [Zn(phba) 2 (btp)] 2 (1) and [Cd(phba) 2 (btp)(H 2 O)] n (2) have been synthesized by using 1,3-bis(1,2,4-triazol-1yl)propane (btp) and 4-hydroxybenzoate (phba). 1 contains the neutral dimer Zn 2 (btp) 2 metallacycle, while 2 forms the one-dimensional zigzag chain structure. 1 an