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Syntheses and reactivity of ruthenium hydride complexes containing chelating triphosphines. 1. Characterization of the molecular dihydrogen complex RuH2(H2)(Cyttp). Cyttp = PhP(CH2CH2CH2P(c-C6H11)2)2

โœ Scribed by Jia, Guochen; Meek, Devon W.


Book ID
126868919
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
315 KB
Volume
111
Category
Article
ISSN
0002-7863

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Structure and reactivity of cyanocuprate
โœ Claudia M.P. Kronenburg; Johann T.B.H. Jastrzebski; Gerard van Koten ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 83 KB

The 2:1 cyanocuprate [Ar 2 Cu(CN)Li 2 (THF) 4 ] `(1, Ars[C 6 H 4 CH 2 NMe 2 -2] y ) is obtained as the only product in the reaction of two equivalents of ArLi with one equivalent of CuCN in tetrahydrofuran (THF) at y788C. The X-ray crystal structure reveals an ionic polymeric chain consisting of con