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Syntheses and reactions of hydrazine and diazene complexes of tungsten. The first example of monodentate coordination of diazene

✍ Scribed by Smith, Milton R.; Cheng, Tan Yun; Hillhouse, Gregory L.

Book ID
118131357
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
660 KB
Volume
115
Category
Article
ISSN
0002-7863

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## Abstract The reaction of [ReCl~2~(OCH~3~)(NO)(PPh~3~)~2~] with phosphane in the presence of NaBH~4~ gives different dihydride [ReH~2~(NO){PPh~2~(OEt)}~3~] (1) and alkoxy‐hydride [ReH(OR^1^)(NO)P~3~] (2, 3) [R^1^ = CH~3~, C~2~H~5~; P = PPh(OEt)~2~, P(OEt)~3~] derivatives depending on the nature o