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Side-on Bound Diazene and Hydrazine Complexes of Ruthenium

✍ Scribed by Field, Leslie D.; Li, Hsiu L.; Dalgarno, Scott J.

Book ID
127303868
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
912 KB
Volume
49
Category
Article
ISSN
0020-1669

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## Abstract The reaction of [ReCl~2~(OCH~3~)(NO)(PPh~3~)~2~] with phosphane in the presence of NaBH~4~ gives different dihydride [ReH~2~(NO){PPh~2~(OEt)}~3~] (1) and alkoxy‐hydride [ReH(OR^1^)(NO)P~3~] (2, 3) [R^1^ = CH~3~, C~2~H~5~; P = PPh(OEt)~2~, P(OEt)~3~] derivatives depending on the nature o