Syntheses and properties of N-vinylpyrrolidione-g-EPDM and its modified polymer

✍ Scribed by Jin Park; Jong-Gu Park; Chang-Sik Ha; Won-Jei Cho

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 231 KB
• Volume: 72
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19990531)72:9<1177::aid-app7>3.0.co;2-h

✦ Synopsis

The graft copolymerizations of N-vinylpyrrolidione(NVP) onto ethylenepropylene-diene terpolymer (EPDM) were carried out with benzoyl peroxide (BPO) as an initiator in toluene. The synthesized EPDM-g-NVP (ENVP) was characterized by infrared (IR) spectroscopy and gel permeation chromatography (GPC). The effects of initiator and monomer concentrations, reaction time, and temperature were investigated in the graft copolymerization. The highest graft efficiency was obtained at 0.04 mol of NVP, 2 g of EPDM, 2 wt % of BPO and 80°C for 72 h. Modified ENVP (MENVP) was obtained by the reaction of ENVP and KOH in MeOH. Properties of EPDM, ENVP, and MENVP were investigated by a thermogravimetric analyzer (TGA), an instron tensile tester, a Fade-O-Meter, and a UV spectrophotometer. Tensile strength and light resistance of ENVP were better than those of MENVP. The dyeability of polymers was increased in following order: MENVP Ͼ ENVP Ͼ EPDM.