Radikalische Cyclisierung von Dienen, VI
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Weinges, Klaus ;Schwarz, Georg
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Article
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1993
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John Wiley and Sons
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English
⚖ 468 KB
Radical‐Type Cyclization of Dienes, VI. – Substrate‐Controlled Asymmetric Synthesis of (3a__S__,6a__R__)‐(+)‐3,3a,6,6a‐Tetrahydro‐2__H__‐cyclopenta[__b__]furan‐2‐one (__R__)‐(−)‐Carvone (1) was converted via straightforward reactions into 10‐hydroxycarvone (4) which was cyclized to 5 via the mercur