Syntheses and molecular structures of 2- [1′-N-(alkyl)imino-2′,2′,2′-trifluoroethyl] phenols
✍ Scribed by Ralph-Matthias Schoth; Enno Lork; Gerd-Volker Röschenthaler
- Book ID
- 107794607
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 402 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0022-1139
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📜 SIMILAR VOLUMES
## Abstract Three different routes were probed for the synthesis of enantiomerically enriched 2‐(1‐aminoethyl)phenols and their methyl ethers. The first route centers on diastereoselective nucleophile addition to chiral imines. The second route has as key steps the enantioselective reduction of a k
A number of 2-N-alkylamino-or 2-N-phenylamino-, 2-N,N-RCH 2 CϵCLi, or the lithiated allene, tBuCH=C=CHLi, and isothiocyanate, RЈN=C=S, in tetrahydrofuran and subse-dialkylamino-, and 2-N-alkyl-N-phenylaminothiophenes have been prepared in good yields by adding a solution of quently hydrolyzing the r