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Syntheses and Crystal Structures of the Monoammoniates of Lithium Halides: LiBr×NH3 and LiI×NH3.
✍ Scribed by Herbert Jacobs; Martin Friedriszik
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 54 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Single crystals of AlBr 3 • NH 3 and AlI 3 • NH 3 sufficient in size for X-ray structure determinations were obtained by evaporation/sublimation of the respective compound from its melt. The ammoniates were synthesized by the reaction of the pure halide with NH 3 at Ϫ78°C and following homogenizatio
## Abstract For Abstract see ChemInform Abstract in Full Text.
1997 structure structure (solids and liquids) D 2000 ## 14 -006 Synthesis, Crystal Structure, and IR Investigations of ((NH3)5V-O-V( NH3)5)I4•NH3 and ((NH3)5Ti-O-Ti(NH3)5)I4•NH3. -Single crystals of the novel title compounds are prepared by room-temp. reaction of VI2 or TiI3, resp., with liquid a