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Syntheses and crystal structures of the compounds In3.7Mo15S19, In1.6Rb2Mo15S19, In2.2CsMo15S19 and ScTl2Mo15S19 containing Mo6 and Mo9 clusters

โœ Scribed by Diala Salloum; Patrick Gougeon; Thierry Roisnel; Michel Potel


Book ID
116597903
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
692 KB
Volume
383
Category
Article
ISSN
0925-8388

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๐Ÿ“œ SIMILAR VOLUMES


K2Mo15S19: a novel ternary reduced molyb
โœ Picard, S. ;Gougeon, P. ;Potel, M. ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 366 KB

K 2 Mo 15 S 19 (potassium molybdenum sulยฎde) crystallizes in the trigonal space group R3c and belongs to the In 2 Mo 15 Se 19 structure type. Its crystal structure consists of an equal mixture of Mo 6 S 8 and Mo 9 S 11 cluster units interconnected through MoรS bonds. The K + cations occupy large voi