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Syntheses and Characterization of Oxo-Centered Triruthenium Compounds with Orthometalated Bipyridine

โœ Scribed by Chen, Jing-Lin; Zhang, Xu-Dong; Zhang, Li-Yi; Shi, Lin-Xi; Chen, Zhong-Ning

Book ID
127190341
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
119 KB
Volume
44
Category
Article
ISSN
0020-1669

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The organotin(IV) chlorides R n SnCl 4-n (n = 3, R = Ph, PhCH 2 , n-Bu; and n = 2, R = n-Bu, Ph, PhCH 2 ) react with 4,4 -bipyridine (4 4-bpy) to give [(Ph 3 SnCl) 2 (4,4 -bpy) [(n-Bu) 3 SnCl] 2 (4,4 -bpy) (3), [(n-Bu) 2 SnCl 2 (4,4 -bpy)] ( 4), [Ph 2 SnCl 2 (4,4 -bpy)] ( 5), and [(PhCH 2 ) 2 SnCl 2