Spectroscopic, Electrochemical, and DFT Studies of Oxo-Centered Triruthenium Cluster Complexes with a Bis(tridentate) Triazine Ligand

Iron Complexes Containing the Ligand N,N

Iron Complexes Containing the Ligand N,N′-Bis(6-methyl-2-pyridylmethyl)-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine: Structural, Spectroscopic, and Electrochemical Studies, Reactivity with Hydrogen Peroxide and the Formation of a Low-Spin Fe−OOH Complex

✍ Véronique Balland; Frédéric Banse; Elodie Anxolabéhère-Mallart; Martine Nierlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB

## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole