## Abstract A series of naphthalenediyl‐1,8‐bis(phosphine oxides) 1‐RR′P(:O)(C~10~H~6~)‐8‐P(:O)RR′ (R = R′ = Me (2a), Et (2b), iPr (2c), Cy (2d), Ph (2f) and R = tBu, R′ = Ph (2e) was prepared by oxidation of the corresponding bis(phosphines) 1a–f with molecular oxygen or H~2~O~2~·(H~2~N)~2~C(:O) a
Syntheses and characterization of bis(trifluoromethyl)phosphino naphthalenes and acenaphthenes
✍ Scribed by Wawrzyniak, Piotr; Slawin, Alexandra M. Z.; Woollins, J. Derek; Kilian, Petr
- Book ID
- 111680089
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 284 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/b916425a
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## Abstract Compounds bearing the structural motif of 2,6‐bis(phosphino)phenol have been synthesized via two general methods. Double lithium‐halogen exchange occurred in low‐temperature reactions of O‐protected (by methyl‐ or tetrahydropyranyl groups) 2,6‐dibromo‐4‐methylphenol derivatives with BuL