ChemInform Abstract: Oxidation Reactions of 1,8-Bis(phosphino)naphthalenes: Syntheses and Molecular Structures of Bis(phosphine oxides) and of a Bis(phosphine sulfide).
β Scribed by Atilla Karacar; Matthias Freytag; Holger Thoennessen; Jan Omelanczuk; Peter G. Jones; Rainer Bartsch; Reinhard Schmutzler
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Q 1070 ## 47 -125 Molecular Structure and Reactions of 1,1'-Bi(acenaphthen-1-ylidene)-2,2'-dione. -The molecular structure of title compound (I) is investigated by X-ray crystallography and semi-empirical calculations. Its tetrasubstituted ene double bond displays unexpected propensity toward [4 +