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Syntheses and absolute configurations of tricyclo[4.3.0.03,7]nonane ("brexane"), 3-oxatricyclo[4.3.0.04,9]nonane ("3-oxabrexane"), and tricyclo[4.2.0.03,7]octan-2-one ("norbrexan-2-one")

โœ Scribed by Nakazaki, Masao.; Naemura, Koichiro.; Kadowaki, Hisazi.


Book ID
120162258
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
849 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract The synthesis of 2,7,9โ€trimethylenetricyclo[4.3.0.0^3,8^]nonane (8), 7,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonanโ€2โ€one (15), and 2,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonโ€4โ€ene (9) has been achieved. The first key step of the synthesis is a Dielsโ€Alder reaction. In the reaction sequence a