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Rearrangements of 1,2,3,4-tetrachloropentacyclo[4.3.0.02,5.03,8.04,7]nonan-9-one

โœ Scribed by Dauben, William G.; Reitman, Larry N.


Book ID
127256264
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
587 KB
Volume
40
Category
Article
ISSN
0022-3263

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## Abstract The synthesis of 2,7,9โ€trimethylenetricyclo[4.3.0.0^3,8^]nonane (8), 7,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonanโ€2โ€one (15), and 2,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonโ€4โ€ene (9) has been achieved. The first key step of the synthesis is a Dielsโ€Alder reaction. In the reaction sequence a