**Synthesis of optically active natural carotenoids and structurally related compounds. VI. Synthesis of Picrocrocin** The synthesis of picrocrocin (**6**), the bitter essence of saffron (__Crocus sativus__ L.) is reported utilizing (3__R__)‐3‐hydroxy‐β‐cyclogeranyl acetate (**3**) as a readily ava
Synthese von optisch aktiven, natürlichen Carotinoiden und strukturell verwandten Verbindungen. III. Synthese von (+)-Abscisinsäure, (−)-Xanthoxin, (−)-Loliolid, (−)-Actinidiolid und (−)-Dihydroactinidiolid
✍ Scribed by Frnak Kienzle; Hans Mayer; Rudolf E. Minder; Hans Thommen
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- German
- Weight
- 712 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Synthesis of optically active natural carotenoids and structurally related compounds. III. Synthesis of (+)‐abscisic acid, (−)‐xanthoxin, (−)‐loliolide, (−)‐actinidiolide, and (−)‐dihydroactinidiolide
The syntheses of (+)‐abscisic acid (1), (−)‐xanthoxin (2), (−)‐loliolide (3), (−)‐actinidiolide (4), and of (−)‐dihydroactinidiolide (5) from one common starting material are reported. The syntheses yield also some enantiomeric or diastereomeric analogues.
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