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Synthese von optisch aktiven, natürlichen Carotinoiden und strukturell verwandten Naturprodukten. VII. Synthese von (3R)-3-Hydroxyretinol, (3R)-3-Hydroxyretinal und (3R)-3-Hydroxyretinsäure

✍ Scribed by Hans Mayer; Jean-Marie Santer

Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
379 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis

Synthesis of optically active natural carotenoids and structurally related compounds

VII. Synthesis of (3R)-3-hydroxyretinol, (3R)d-hydroxyretinal and (3R)-3-hydroxyretinoic acid

Summary

The synthesis of (3R)-3-hydroxyretino1( 7), (3R)-3-hydroxyretinal( 9) and (3R)-3hydroxyretinoic acid (5) according to the building principle C,, + C5 = C,, is reported utilizing the optically active C15-phosphonium salt 2 and the C,-aldehyde ester 3.

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Fur eine Zusammenstellung dcr ncucrcn Litcratur vgl. [2].

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