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Citrus-Carotinoide. 2. Mitteilung. Synthese von (3R)-β-Citraurin, (3R)-β-Citraurol und (3R)-β-Citraurinin; Aufklärung der Konfiguration von Citrus-Carotinoiden

✍ Scribed by Hanspeter Pfander; Andreas Lachenmeier; Martin Hadorn


Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
439 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis


Citrus‐Carotenoids. Synthesis of (3__R__)‐β‐Citraurin, (3__R__)‐β‐Citraurol and (3__R__)‐β‐Citraurinene; Determination of the Configuration of Citrus‐Carotenoids

(3__R__)‐β‐Citraurin, (3__R__)‐β‐citraurol and (3__R__)‐β‐citraurinene were prepared starting from (3__R__)‐3‐acetoxy‐β‐ionone. Comparison of the chiroptical data of β‐citraurin from orange peels with those of the synthetic compound confirmed the 3__R__‐configuration of the natural pigment.