Structures 1 and 2 are self-complementary but they are also mutually well suited. The hybrid aggregate (1 -2) of 1 and 2 is shown in Scheme 3. The calculated structure of the pear shaped 1 -2 adducts suggests the formation of only six "strong" hydrogen bonds. The two additional bonds are significant
β¦ LIBER β¦
Synthese und Struktur eines freien Germacyclopentadienid-Ions im Kristall: [Li([12]krone-4)2][C4Me4GeSi(SiMe3)3]
β Scribed by William P. Freeman; Prof. Dr. T. Don Tilley; Frederick P. Arnold; Prof. Dr. Arnold L. Rheingold; Dr. Peter K. Gantzel
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 385 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0044-8249
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81 Kristallstrukturdat~n fur 2: (L =12.837(3). b = 13.728(2). c = 24.178(5) A, gruppe PI: Z = 4. Die Struktur wurde mit der Patterson-Methode gelnst. fur 832 Variable verfeinert, 6237 Reflexe mit F2 3olF'I. R = 0.0525, R, = 0.0625 und GOF = 1.74. Die Struktur besteht aus zwei kristallographisch vone