Synthese und Kristallstrukturen von (3-Methylpyridinium)3[DyCl6] und (3-Methylpyridinium)2[DyCl5(Ethanol)]
✍ Scribed by Jens Hallfeldt; Werner Urland
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 121 KB
- Volume
- 627
- Category
- Article
- ISSN
- 0372-7874
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## Abstract 3‐Amino‐ und 5‐Amino‐4‐methyl‐6‐morpholino‐salicylsäuremethylester (**1c, 1e**) lassen sich durch katalytische Hydrierung mit Platin(IV)‐oxid aus den entsprechenden 3‐ bzw. 5‐Nitroso‐ oder Nitroestern **1a**, **1b**, **1d** gewinnen. Durch Reduktion von 4‐Methyl‐6‐morpholino‐3,5‐dinitro
Single crystals of (Ph 4 P)TbCl 4 (CH 3 CN) (1) and (Ph 4 P)DyCl 4 (CH 3 CN) (2) are obtained from the reaction of TbCl 3 and DyCl 3 , respectively, with tetraphenylphosphonium chloride in acetonitrile. The crystal structures [monoclinic, P2 1 /n (Nr. 14), Z = 4, a = 1065.5(4)/997.3(5) (1/2); b = 21
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