𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthese und Kristallstruktur von [KNPPh3]6 · 4 C7H8

✍ Scribed by Soheila Chitsaz; Bernhard Neumüller; Kurt Dehnicke

Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
75 KB
Volume
625
Category
Article
ISSN
0372-7874

No coin nor oath required. For personal study only.

✦ Synopsis

KNPPh 3 ] 6 ´4 C 7 H 8 (1) has been prepared from HNPPh 3 and potassium hydride in boiling toluene forming pale yellow moisture sensitive crystals, which were characterized by a crystal structure determination. Space group P1, Z = 2, lattice dimensions at ±83 °C: a = 1517.9(2), b = 1894.0(2), c = 2150,4(2) pm, α = 84.39(1)°, b = 89.31(1)°, c = 89.97(1)°, R 1 = 0.0684. 1 forms a K 6 N 6 skeleton of a dou-ble cube with a common face of two K and two N atoms, the latter being fivefold coordinated by four K atoms and the P atom of the PPh 3 groups.

📜 SIMILAR VOLUMES

Synthese und Kristallstruktur von Y(HSO4
Synthese und Kristallstruktur von Y(HSO4)3-I und Y(HSO4)3 · H2O
✍ Mathias S. Wickleder 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 128 KB 👁 1 views

Inhaltsu È bersicht. Y(HSO 4 )-I bildet sich in Form lattenfo È rmiger Einkristalle bei der Reaktion von konz. Schwefelsa È ure mit Y 2 O 3 bei 200 °C. Y(HSO 4 ) 3 -I kristallisiert orthorhombisch (Pbca, Z = 8, a = 1201,5(1), b = 953,76(8), c = 1650,4(1) pm, R all = 0,0388). Dabei ist Y 3+ von acht

Synthese und Kristallstruktur von Na2Zn(
Synthese und Kristallstruktur von Na2Zn(OH)4
✍ R. Stahl; R. Niewa; H. Jacobs 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 78 KB 👁 1 views

Professor Klaus-Ju È rgen Range zum 60. Geburtstag gewidmet Inhaltsu È bersicht. Aus heiûgesa È ttigten Natriumhydroxozinkatlo È sungen wurden bei Raumtemperatur pla È ttchenfo È rmige farblose Kristalle von Na 2 Zn(OH) 4 erhalten. An ihnen wurde ro È ntgenographisch die Struktur einschlieûlich alle

Synthese und Koordination von 2-Acetylim
Synthese und Koordination von 2-Acetylimino-1,3-dimethylimidazolin. Die Kristallstruktur von [Cu4I4(C7H11N3O)2] [1]
✍ Norbert Kuhn; Riad Fawzi; Martin Grathwohl; Heike Kotowski; Manfred Steimann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 72 KB 👁 2 views

2-Acetylimino±1,3-dimethylimidazoline (2, ImNAc) obtained from 1,3-dimethyl-2-iminoimidazoline (1) and acetyl chloride forms with CuI the stepped cubane type complex [Cu 4 I 4 (ImNAc) 2 ] (3); the X-ray structure of 3 is reported.

Synthese und Kristallstruktur von [Na3(H
Synthese und Kristallstruktur von [Na3(H2O)6,5(EtOH)][PhSnS3] · 3 EtOH
✍ Ralf Hauser; Kurt Merzweiler 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 98 KB 👁 1 views

Ph 4 Sn 4 S 6 reacts with Na 2 S ´5 H 2 O in aqueous acetone to form Na 3 [PhSnS 3 ]. Recrystallization of the crude product from ethanol leads to colourless needles of [Na 3 (H 2 O) 6,5 (EtOH)][PhSnS 3 ] ´3 EtOH 1. The crystal structure of 1 was determined by X-ray diffraction. 1 consists of [PhSnS

Synthese, Eigenschaften und Struktur von
Synthese, Eigenschaften und Struktur von [Li(OC4H8)4][((CH3)3Si)3C–InBr3]
✍ A. Walz; K. W. Klinkhammer; J. Weidlein 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 84 KB

The reaction of InBr 3 with LiR\* ´(THF) n (R\* = ±C(SiMe 3 ) 3 , THF = OC 4 H 8 ) in a 1 : 1 molar ratio forms [Li(THF) 4 ][R\*InBr 3 ] in good yield. The properties and some spectroscopic data ( 1 H, 13 C, 29 Si, 7 Li±NMR, IR and Raman) of this trisyl-tribromoindate are given and the crystal struc