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Synthese und Einkristallstrukturanalyse von Bis(benzyltrimethylammonium)fullerid-Ammoniakat; (BzlNMe3)2C60 · 3 NH3

✍ Scribed by Klaus Himmel; Martin Jansen

Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
100 KB
Volume
624
Category
Article
ISSN
0372-7874

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✦ Synopsis

The title compound has been prepared from K 2 C 60 by ion exchange of potassium for benzyltrimethylammonium cations in liquid ammonia. X-ray single crystal structure analysis reveals highly ordered fulleride ions forming a layerlike arrangement with short inter-fullerene distances. The an-ionic fulleride layers are separated by layers of benzyltrimethylammonium cations and ammonia.

📜 SIMILAR VOLUMES

On the Geometry of the Fulleride Dianion
On the Geometry of the Fulleride Dianion C602– in Crystalline Fullerides – Syntheses and Crystal Structures of [M(NH3)6]C60 · 6 NH3 (M = Mn2+, Cd2+)
✍ Klaus Himmel; Martin Jansen 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 275 KB

The fullerides [M(NH 3 ) 6 ]C 60 (M = Mn 2+ , Cd 2+ ) have been An inspection of the fulleride dianions with respect to geometric deformations in the title compounds and three synthesized by ion exchange in liquid ammonia and analyzed by X-ray single-crystal diffraction. With both further independen