✦ LIBER ✦
On the Geometry of the Fulleride Dianion C602– in Crystalline Fullerides – Syntheses and Crystal Structures of [M(NH3)6]C60 · 6 NH3 (M = Mn2+, Cd2+)
✍ Scribed by Klaus Himmel; Martin Jansen
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 275 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
The fullerides [M(NH 3 ) 6 ]C 60 (M = Mn 2+ , Cd 2+ ) have been An inspection of the fulleride dianions with respect to geometric deformations in the title compounds and three synthesized by ion exchange in liquid ammonia and analyzed by X-ray single-crystal diffraction. With both further independent determinations has led to the conclusion that no significant static Jahn-Teller distortion is present. complex cations the C 60 2-units are in fixed orientations, and their geometries have been determined with good accuracy.