Syndiotactic specific polymerization of styrene: driving energy of the steric control and reaction mechanism

✍ Scribed by Pasquale Longo; Antonio Proto; Adolfo Zambelli

• Book ID: 102939171
• Publisher: John Wiley and Sons
• Year: 1995
• Tongue: English
• Weight: 702 KB
• Volume: 196
• Category: Article
• ISSN: 1022-1352
• DOI: 10.1002/macp.1995.021960924

✦ Synopsis

Abstract

The stereoregularity of polystyrenes prepared in the presence of different syndiotactic specific homogeneous catalysts, at different temperatures and monomer concentrations, has been evaluated by ^13^C NMR. It is confirmed that the statistical model of the stereospecific propagation is first‐order Markovian. The stereoregularity of the polymers decreases while increasing the polymerization temperature and is affected by the concentration of the monomer, by the ligands of the transition metal precursor of the catalyst, and is higher in the presence of titanium based catalysts. Polymerization of substituted styrenes is increasingly stereospecific in the order p‐chlorostyrene < styrene < p‐methylstyrene. The results strongly support the polyinsertion mechanism proposed in a previous paper by some of us.