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syn-Allylstannation of N-Acyliminium Intermediates by Tributyl[γ-(silyloxy)allyl]stannanes: A Key Reaction for the Diastereoselective Synthesis of Polyhydroxypiperidines and Polyhydroxyazepanes

✍ Scribed by Floris Chevallier; Alexandre Lumbroso; Isabelle Beaudet; Erwan Le Grognec; Loïc Toupet; Jean-Paul Quintard

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
660 KB
Volume
2011
Category
Article
ISSN
1434-193X

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ChemInform Abstract: syn-Allylstannation
ChemInform Abstract: syn-Allylstannation of N-Acyliminium Intermediates by Tributyl[γ-(silyloxy)allyl]stannanes: A Key Reaction for the Diastereoselective Synthesis of Polyhydroxypiperidines and Polyhydroxyazepanes.
✍ Floris Chevallier; Alexandre Lumbroso; Isabelle Beaudet; Erwan Le Grognec; Loic 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 69 KB 👁 1 views

## Abstract The allylstannation of N‐acyliminium intermediates affords the expected adducts with high syn‐selectivity.