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ChemInform Abstract: syn-Allylstannation of N-Acyliminium Intermediates by Tributyl[γ-(silyloxy)allyl]stannanes: A Key Reaction for the Diastereoselective Synthesis of Polyhydroxypiperidines and Polyhydroxyazepanes.

✍ Scribed by Floris Chevallier; Alexandre Lumbroso; Isabelle Beaudet; Erwan Le Grognec; Loic Toupet; Jean-Paul Quintard


Publisher
John Wiley and Sons
Year
2011
Weight
69 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The allylstannation of N‐acyliminium intermediates affords the expected adducts with high syn‐selectivity.