Symmetry rules for chiral aliphatic amines and their salts
β Scribed by R. G. Kostyanovskii; I. M. Gella; V. I. Markov
- Book ID
- 112437080
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 293 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
## Abstract Substrate specificity of the Οβaminotransferase obtained from __Vibrio fluvialis__ (ΟβAT__Vf__) was rationally redesigned for the kinetic resolution of aliphatic chiral amines. ΟβAT__Vf__ showed unique substrate specificity toward aromatic amines with a high enantioselectivity (__E__β>β
Ln (C-propylene carbonate solution achin aliphztic ketones and thioketones with near-C\*, symmetry givs positive II-\* R\* circuku dictioism monosignate bands while those with lower symmetry give negative bands and centrosymnietric dicarbonyl compounds are optically inactive. A mechAsm for induction