✦ LIBER ✦

Symmetry in H+5 and D+5 Complexes

✍ Scribed by P. Soldan

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 412 KB
Volume: 168
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1994.1276

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✦ Synopsis

A symmetry analysis of the (\mathrm{H}{5}^{+})and (\mathrm{D}{5}^{+})complexes in a model with one large amplitude motion, an internal rotation, is presented. New presentations of the molecular symmetry group (G_{16}) and its extended molecular symmetry group are determined. Symmetry coordinates and symmetry adapted expansions of the potential and electric dipole moment components are derived. Selection rules are applied to the electric dipole transitions. Classifications of vibrational, rotational, and nuclear spin states including nuclear spin statistical weights are presented. (c) 1994 , Academic Press. Inc.

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