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Symmetry Analysis of the Vibrational Dynamics of the H3D2+and H2D3+Complexes

✍ Scribed by P. Soldán; V. špirko; W.P. Kraemer

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
171 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

A symmetry analysis of the H3 D2 + and H2 D3 + complexes in a model with one large amplitude motion, the propeller-like internal rotation, is presented. Symmetry coordinates and symmetry adapted polynomial expansions of the potential, dipole moment, and polarizability functions are derived within the framework of the extended molecular symmetry group G 3 (2, 2) using the projection operator and Molien function techniques.

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