Symmetry analysis of sigmatropic rearrangements

✍ Scribed by Chia-Chung Sun; Wei-Guo Sun; Jing-Chang Zhang; Guang-Zhu Jin

• Book ID: 104580744
• Publisher: John Wiley and Sons
• Year: 1982
• Tongue: English
• Weight: 387 KB
• Volume: 22
• Category: Article
• ISSN: 0020-7608
• DOI: 10.1002/qua.560220606

✦ Synopsis

Abstract

Two small groups (E, σ~ν~) and (E, C~2~) are proposed to describe the orbital symmmetry of the whole reaction paths with respect to suprafacial and antarafacial sigmatropic rearrangements. Furthermore, the symmetries of the two small groups are extended to the systems as a many body treatment performed by Matsen.