Sigmatropic rearrangements of diazenes
โ Scribed by Baldwin, Jack E.; Brown, James Edward; Hoefle, Gerhard
- Book ID
- 127316157
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 269 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract Review: 54 refs.
Monosubstituted hydrazones (II) obtained by alkali fiaaion of l,%di-alQlsulphoacid hydrazides (I) have been considered products of isomeric transformation of the intermediate reactive aminonitrenes (111)1'3: RCH2, OH-RCH2, Hi'
## Abstract Two small groups (__E__, ฯ~ฮฝ~) and (__E__, __C__~2~) are proposed to describe the orbital symmmetry of the whole reaction paths with respect to suprafacial and antarafacial sigmatropic rearrangements. Furthermore, the symmetries of the two small groups are extended to the systems as a m