Symmetrically bridged bis-N-heterocyclic carbene rhodium (I) complexes and their catalytic application for transfer hydrogenation reaction
✍ Scribed by Nadežda B. Jokić; Mei Zhang-Presse; Serena L.M. Goh; Claudia S. Straubinger; Bettina Bechlars; Wolfgang A. Herrmann; Fritz E. Kühn
- Book ID
- 116680207
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 554 KB
- Volume
- 696
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru
## Abstract Di‐ and trinuclear complexes of copper(I) bearing bis‐ or tris‐N‐heterocyclic carbene ligands have been prepared and evaluated as catalysts in nitrene transfer reactions from PhI=NTs to unsaturated and saturated substrates (olefin aziridination and C–H bond amidation) and carbene transf